Please use this identifier to cite or link to this item:
http://paper.sci.ui.ac.id/jspui/handle/2808.28/175
Title: | Microfluidic platform for environmental contaminants sensing and degradation based on boron-doped diamond electrodes |
Authors: | Sánchez, Mariana Medina Martinez, Carmen C. Mayorga Watanabe, Takeshi Tribidasari, Ivandini A. Honda, Yuki Pino, Flavio Nakata, Kazuya Fujishima, Akira Einaga, Yasuaki Merkoçi, Arben |
Keywords: | Atrazine detection Atrazine degradation Biosensor Boron-doped diamond electrode Microfluidics Platinum nanostructured particles |
Issue Date: | Jan-2016 |
Publisher: | Pergamon Press Ltd. |
Series/Report no.: | Volume 75; |
Abstract: | We have developed a lab-on-a-chip (LOC) platform for electrochemical detection and degradation of the pesticide atrazine (Atz). It is based on boron-doped diamond (BDD) electrodes and a competitive magneto-enzyme immunoassay (EIA) that enables high sensitivity. To detect the enzymatic reaction, we employed a BDD electrode modified with platinum nanoparticles (PtNPs), as a highly conductive catalytic transducer. Chronoamperometry revealed a limit of detection (LOD) of 3.5 pM for atrazine, which, to the best of our knowledge, is one of the lowest value published to date. Finally, we degraded Atz in the same platform, using a bare BDD electrode that features remarkable corrosion stability, a wide potential window, and much higher O2 overvoltage as compared to conventional electrodes. These characteristics enable the electrode to produce a greater amount of HO• on the anode surface than do conventional electrodes and consequently, to destroy the pollutant more rapidly. Our new LOC platform might prove interesting as a smart system for detection and remediation of diverse pesticides and other contaminants. |
URI: | http://paper.sci.ui.ac.id/jspui/handle/2808.28/175 |
ISSN: | 0956-5663 |
Appears in Collections: | Journal Collection |
Files in This Item:
File | Description | Size | Format | |
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Ivandini.Biosensors and Bioelectronics.2016.pdf | 2,87 MB | Adobe PDF | View/Open Request a copy |
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